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C–H Bonds Phosphorylation of Ketene Dithioacetals
Organic Letters ( IF 4.9 ) Pub Date : 2015-03-31 00:00:00 , DOI: 10.1021/acs.orglett.5b00728
Liping Zhu 1 , Hongmei Yu 1 , Quanping Guo 1 , Qiao Chen 1 , Zhaoqing Xu 1 , Rui Wang 1, 2
Affiliation  

C–H bond phosphorylation of ketene dithioacetals was achieved under transition-metal-free or AgNO3 mediated conditions. Synthetic transformations of the coupling product provided promising methods for the construction of highly functionalized phosphorylated N-heterocycles and tetrasubstituted alkenes.

中文翻译:

甲乙二硫缩醛的C–H键磷酸化

乙烯酮二硫缩醛的C–H键磷酸化是在无过渡金属或AgNO 3介导的条件下实现的。偶联产物的合成转化为构建高度官能化的磷酸化的N-杂环和四取代的烯烃提供了有希望的方法。
更新日期:2015-03-31
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