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Unique Octupolar 2D-Polymer Frameworks as Mixed Conductors and Metal-Free Catalysts for Dual-Promoted Li and S Electrochemistry: Multi-regulation Role of Ethoxylation Chemistry
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2023-09-10 , DOI: 10.1002/anie.202312016
Cong Liu 1 , Chunshao Mo 1 , Linfeng Zhong 1 , Xiaoqi Gong 1 , Yang Zhang 1 , Xiaotong Wang 1 , Fan Yang 2 , Jing Li 3 , Jiang Lu 1 , Dingshan Yu 1
Affiliation  

A new class of versatile cyano-vinylene-linked octupolar 2D-polymer framework (Cyano-OCF-EO) has been explored as both efficient mixed ionic/electronic conductors and metal-free sulfur evolution catalysts via ethoxylation chemistry, which enables a novel multifunctional separator interlayer to simultaneously tune bidirectional sulfur redox kinetics and Li ion flux for advanced Li−S cells.

中文翻译:

独特的八极二维聚合物框架作为混合导体和无金属催化剂,用于双促进锂和硫电化学:乙氧基化化学的多重调节作用

一种新型多功能氰基-亚乙烯基连接的八极二维聚合物框架(氰基-OCF-EO)已被探索作为有效的混合离子/电子导体和通过乙氧基化化学的无金属硫析出催化剂,这使得新型多功能隔膜成为可能中间层可同时调节先进 Li−S 电池的双向硫氧化还原动力学和锂离子通量。
更新日期:2023-09-10
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