Reticular chemistry within three-dimensional covalent organic frameworks for multiple applications,Journal of Materials Chemistry A

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Reticular chemistry within three-dimensional covalent organic frameworks for multiple applications
Journal of Materials Chemistry A ( IF 10.7 ) Pub Date : 2023-09-12 , DOI: 10.1039/d3ta04395a
Xiaokang Wang ₁ , Fei Gao ₁ , Zixi Kang ₁ , Weidong Fan ₁ , Daofeng Sun ₁

Affiliation

Compared with two-dimensional (2D) covalent organic frameworks (COFs), three-dimensional (3D) COFs have significant advantages, such as larger specific surface areas, complex interconnected structures, and fully accessible active sites, which have aroused extensive interest of researchers. With the rapid development of various 3D COFs, they exhibit great application prospects in many fields, including but not limited to gas storage and separation, catalysis, fluorescence, batteries, conductivity, and drug delivery. Herein, we summarize the advances in the rational design and synthesis of 3D COFs guided by reticular chemistry and topology to explore potential unexploited structures and provide an overview of recent progress in their multifunctional applications, aiming to expand the potential of 3D COFs in practical applications.

中文翻译：

三维共价有机框架内的网状化学可用于多种应用

与二维（2D）共价有机框架（COF）相比，三维（3D）COF具有显着的优势，例如更大的比表面积、复杂的互连结构和完全可接近的活性位点，引起了研究人员的广泛兴趣。随着各种3D COF的快速发展，它们在许多领域展现出巨大的应用前景，包括但不限于气体储存和分离、催化、荧光、电池、导电性和药物输送。在此，我们总结了在网状化学和拓扑引导下合理设计和合成3D COF的进展，以探索潜在的未开发结构，并概述其多功能应用的最新进展，旨在扩大3D COF在实际应用中的潜力。

更新日期：2023-09-12

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