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Easy Access to Tertiary Amines from Carbonyl Compounds with Substituted Amine-Boranes: A Substrate, Catalyst, and Additive-Free Approach Under Mild Conditions
Chemistry - An Asian Journal ( IF 3.5 ) Pub Date : 2023-09-06 , DOI: 10.1002/asia.202300661
Deep Chowdhury 1 , Arup Mukherjee 1
Chemistry - An Asian Journal ( IF 3.5 ) Pub Date : 2023-09-06 , DOI: 10.1002/asia.202300661
Deep Chowdhury 1 , Arup Mukherjee 1
Affiliation
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An operationally simple and efficient protocol for the transformation of carbonyl compounds to tertiary amines with various secondary amine-boranes is reported. The reaction proceeds at room temperature and requires a short reaction time under mild conditions. The reaction encompasses a broad substrate scope and furnishes good-to-excellent yields of the amines in a chemoselective fashion.
中文翻译:
使用取代胺硼烷从羰基化合物中轻松获得叔胺:温和条件下的无底物、催化剂和添加剂方法
报道了一种操作简单且有效的方案,用于用各种仲胺硼烷将羰基化合物转化为叔胺。该反应在室温下进行,反应时间短,条件温和。该反应涵盖广泛的底物范围,并以化学选择性方式提供良好至优异的胺产率。
更新日期:2023-09-06
中文翻译:

使用取代胺硼烷从羰基化合物中轻松获得叔胺:温和条件下的无底物、催化剂和添加剂方法
报道了一种操作简单且有效的方案,用于用各种仲胺硼烷将羰基化合物转化为叔胺。该反应在室温下进行,反应时间短,条件温和。该反应涵盖广泛的底物范围,并以化学选择性方式提供良好至优异的胺产率。