Vinylene Carbonate as Synthon in Transition Metal-Catalyzed C−H Bond Activation/Annulation Reactions,Advanced Synthesis & Catalysis

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Vinylene Carbonate as Synthon in Transition Metal-Catalyzed C−H Bond Activation/Annulation Reactions
Advanced Synthesis & Catalysis ( IF 4.4 ) Pub Date : 2023-09-05 , DOI: 10.1002/adsc.202300601
Xiaofan Cui ₁ , Remi Chauvin ₂ , Chao Pi ₁ , Yangjie Wu ₃ , Xiuling Cui ₁

Affiliation

Recently, vinylene carbonate has been developed as a powerful synthon in transition metal-catalyzed C−H bond activation/cyclization reactions. This review introduces recent progress in the use of vinylene carbonate as a reactant, by analyzing and comparing reaction models involving vinylene carbonate as a surrogate of ethynol, acetylene, acetylation reagents or other reactants, while addressing related mechanisms and synthetic applications.

中文翻译：

碳酸亚乙烯酯作为过渡金属催化的 C−H 键活化/成环反应中的合成子

最近，碳酸亚乙烯酯已被开发为过渡金属催化的CH键活化/环化反应中的强大合成子。本文通过分析和比较碳酸亚乙烯酯作为乙醇、乙炔、乙酰化试剂或其他反应物替代物的反应模型，介绍了碳酸亚乙烯酯作为反应物的最新进展，同时讨论了相关机理和合成应用。

更新日期：2023-09-05

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