当前位置: X-MOL 学术Angew. Chem. Int. Ed. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Modulating Ligand-Exchange Dynamics on Metal-Organic Polyhedra for Reversible Sorting and Hybridization of Miktoarm Star Polymers
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2023-09-04 , DOI: 10.1002/anie.202311954
Yuyan Lai 1 , Xiaofeng He 1 , Binghui Xue 1 , Mu Li 1 , Huihui Wang 2 , Wei Huang 2 , Jia-Fu Yin 1 , Mingxin Zhang 2 , Panchao Yin 1
Affiliation  

Metal-organic polyhedra possess logarithmic ligand-exchange dynamics that can only be activated at high temperatures. They have been applied as crosslinker templates for the synthesis of miktoarm star polymers with target compositions by thermal annealing of the mixture of star homo-polymers. The reversible sorting process can be conducted through a typical solvent extraction procedure.

中文翻译:

调节金属有机多面体上的配体交换动力学以实现 Miktoarm 星形聚合物的可逆分选和杂交

金属有机多面体具有对数配体交换动力学,只能在高温下激活。它们已被用作交联剂模板,通过星形均聚物混合物的热退火来合成具有目标成分的miktoarm星形聚合物。可逆分选过程可以通过典型的溶剂萃取程序进行。
更新日期:2023-09-04
down
wechat
bug