The significance of unconventional noncovalent interactions in crystal packing was evidenced using the crystal structure of 1,1′-(1-chloro-4-methoxyphenyl)dibenzene as a case study. The nature, energetics, and cooperativity of a network of weak interactions were evaluated using combined crystallography and dispersion-corrected DFT calculations.

中文翻译：

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非常规非共价相互作用控制：以1,1'-(1-氯-4-甲氧基苯基)二苯晶体结构的晶体学和理论分析为例

以 1,1′-(1-氯-4-甲氧基苯基)二苯的晶体结构为例，证明了非常规非共价相互作用在晶体堆积中的重要性。使用组合晶体学和色散校正 DFT 计算来评估弱相互作用网络的性质、能量和协同性。