A CPP-bipyridine catenane, which consists of [9]CPP and a 2,2′-bipyridine macrocycle, has been synthesized by an active metal template strategy. Catalytic C−H borylation/cross-coupling and metal complexation at the bipyridine macrocycle moiety illustrated the efficient post-functionalization of the [9]CPP-bipyridine catenane. The structural and photophysical properties of the Ag complex of [9]CPP-bipyridine catenane were also studied.

中文翻译：

---

使用活性金属模板策略通过索烯形成对环对苯撑进行非共价改性**

通过活性金属模板策略合成了由[9]CPP和2,2'-联吡啶大环组成的CPP-联吡啶索烯烷。联吡啶大环部分的催化 C−H 硼基化/交叉偶联和金属络合说明了 [9]CPP-联吡啶索烯的有效后官能化。还研究了[9]CPP-联吡啶索烯Ag配合物的结构和光物理性质。