Capture of Singlet Oxygen Modulates Host-Guest Behavior of Coordination Cages,Angewandte Chemie International Edition

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Capture of Singlet Oxygen Modulates Host-Guest Behavior of Coordination Cages
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2023-08-23 , DOI: 10.1002/anie.202309589
Ilma Jahović ₁ , Yuchong Yang ₁ , Tanya K Ronson ₁ , Jonathan R Nitschke ₁

Affiliation

A range of anthracene-based tetrahedral capsules have been shown to react with photogenerated singlet oxygen in a hetero-Diels–Alder reaction. The cage cycloadducts were found to bind an array of guest molecules more weakly than their precursor cages, offering a novel method for stimuli-driven guest uptake and release.

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