Solid oxide electrolysis cells (SOECs) are regarded as a promising technology to realize carbon neutrality since they can electrochemically convert CO₂ to CO. This communication reports a feasible structure of a metal-supported solid oxide electrolysis cell (Ms-SOEC) for CO₂ electrolysis, where a porous 430 stainless steel substrate is coated with perovskite oxide La_0.6Sr_0.4Fe_0.9Mo_0.1O_3-δ (LSFM) introduced by the infiltration method. The LSFM catalyst exhibits a uniform distribution and loose accumulation in the porous metal substrate. This Ms-SOEC with a structure of LSFM-430|YSZ|LSCF-SDC shows a current density of 0.90 A cm⁻² at 800 °C and 1.5 V with an LSFM loading of 6.0 wt%. Meanwhile, a 10-times thermal cycling operation demonstrates good reliability of the configuration. Overall, the metal-based cathode, where 430 stainless steel acts as the mechanical support and infiltrated LSFM perovskite acts as the electrocatalyst for CO₂ electrolysis, could be a viable configuration of Ms-SOECs.

固体氧化物电解池（SOEC）被认为是一种有前途的实现碳中和的技术，因为它们可以通过电化学方式将CO 2 转化_为CO。该通讯报道了一种用于CO ₂的金属支撑固体氧化物电解池（Ms-SOEC）的可行结构电解，其中多孔430不锈钢基底上涂覆有通过渗透法引入的钙钛矿氧化物La _0.6 Sr _0.4 Fe _0.9 Mo _0.1 O _{3-δ (LSFM)。}LSFM催化剂在多孔金属基底中表现出均匀分布和松散堆积。该结构为LSFM-430|YSZ|LSCF-SDC的Ms-SOEC显示出0.90 A cm ^{-2的电流密度}在 800 °C 和 1.5 V 下，LSFM 负载为 6.0 wt%。同时，10次热循环运行表明该配置具有良好的可靠性。总体而言，金属基阴极（其中430不锈钢充当机械支撑件，渗透LSFM钙钛矿充当CO ₂电解的电催化剂）可能是Ms-SOEC的可行配置。