Synthesis of the Key Saccharide Fragments of the Glucuronic Acid-Containing Repeat Unit of Pentosan Polysulfate, a Heparin Sulfate Mimetic,SynOpen

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Synthesis of the Key Saccharide Fragments of the Glucuronic Acid-Containing Repeat Unit of Pentosan Polysulfate, a Heparin Sulfate Mimetic
SynOpen ( IF 2.0 ) Pub Date : 2023-08-21 , DOI: 10.1055/a-2126-0346
Martin Gerhardt Banwell ₁ , Sarah Marshall ₂ , Jas S Ward ₂ , Brett Schwartz ₂

Affiliation

Suitably protected mono- and di-saccharide residues associated with the glucuronic acid-containing repeat unit related to pentosan polysulfate have been prepared. The stereo-controlled coupling, using trichloroacetimidate chemistry, of certain of these is also described and the structure of a disaccharide so-formed has been confirmed by single-crystal X-ray analysis.

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