Technetium isotope ⁹⁹Tc is a main radioactive waste produced in the process of nuclear reaction, which has the characteristics of long half-life and strong environmental mobility, and can be bio-accumulated in organisms, resulting in serious threat to human health and ecosystem. Adsorption method is widely used in the field of removing radionuclides from water due to the advantages of high treatment rate, simple and mature industrial application. In this review paper, the recent advances in research and application of various adsorption materials for ⁹⁹Tc pollution treatment were summarized and analyzed for the first time, including inorganic adsorbents, such as activated carbon, zero-valent iron, metallic minerals, clay minerals, layered double hydroxides (LDHs), tin-based materials, and sulfur-based materials; organic adsorbents, such as porous organic polymers (POPs), covalent-organic frameworks (COFs), metal-organic frameworks (MOFs), and ion exchange resin; and biological adsorbents, such as biopolymers (chitosan, cellulose, alginate), and microbial cells. The performance characteristics and the adsorption kinetics and isotherms of various adsorption materials were discussed. This review could deepen the understanding of the adsorptive removal of ⁹⁹Tc from aqueous solution, and provide a reference for the future research in this field.