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通过掺入冠醚来捕获阳离子以进行离子筛分,从而使金属有机框架膜带电
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2023-08-15 , DOI: 10.1002/anie.202309918
Jiang Li 1, 2 , Yayun Shi 3 , Chenyang Qi 4 , Bowen Zhang 5 , Xiwen Xing 6 , Yuliang Li 2 , Tongdan Chen 2 , Xingnuo Mao 5 , Zhijun Zuo 3 , Xiaoli Zhao 4 , Zhenghui Pan 4 , Libo Li 3 , Xiaowei Yang 1, 4, 5 , Cheng Li 1
Affiliation  

带电金属有机框架(MOF)膜通过包含冠醚来捕获阳离子,从而实现从负电荷到正电荷的反转。结果是增强的Li + /Mg 2+选择性。Li + /Mg 2+选择性的提高与空间效应和静电斥力引起的Li +和Mg 2+之间的能垒偏差的扩大有关。



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更新日期:2023-08-15
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