Advance on nickel- and palladium-catalyzed insertion copolymerization of ethylene and acrylate monomers,Journal of Polymer Science

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Advance on nickel- and palladium-catalyzed insertion copolymerization of ethylene and acrylate monomers
Journal of Polymer Science ( IF 3.9 ) Pub Date : 2023-08-08 , DOI: 10.1002/pol.20230389
Handou Zheng ₁ , Zonglin Qiu ₁ , Donghui Li ₁ , Lixia Pei ₂ , Haiyang Gao ₁

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Nickel- and palladium-catalyzed insertion copolymerization of ethylene and acrylate comonomers for synthesis of ethylene-acrylates copolymers have attracted much academic and industrial interests and remained highly challenging. This review provides an overview of the developments in nickel- and palladium-catalyzed insertion copolymerization of ethylene and acrylate comonomers. Mechanistic interpretation of metal-catalyzed insertion copolymerization of ethylene and acrylate comonomers is described. Late transition metal catalysts are divided to nickel-based and palladium-based catalysts with different chelate ligands. The effects of catalyst structure on copolymerization performance and copolymer microstructure are comprehensively discussed. This review aims to promote the design and development of nickel and palladium catalysts for ethylene/acrylate copolymerizations and synthesis of ethylene-acrylates copolymers.

中文翻译：

镍、钯催化乙烯与丙烯酸酯单体插入共聚研究进展

用于合成乙烯-丙烯酸酯共聚物的镍和钯催化乙烯和丙烯酸酯共聚单体的插入共聚吸引了许多学术和工业界的兴趣，并且仍然具有很高的挑战性。本综述概述了镍和钯催化乙烯和丙烯酸酯共聚单体插入共聚的进展。描述了金属催化乙烯和丙烯酸酯共聚单体插入共聚的机理解释。后过渡金属催化剂分为具有不同螯合配体的镍基和钯基催化剂。综合讨论了催化剂结构对共聚性能和共聚物微观结构的影响。本综述旨在促进用于乙烯/丙烯酸酯共聚和乙烯-丙烯酸酯共聚物合成的镍和钯催化剂的设计和开发。

更新日期：2023-08-08

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