Wastewater disposal in the ecosystem affects aquatic and human life, which necessitates the removal of the contaminants. Eliminating wastewater contaminants using biochar produced through the thermal decomposition of lignocellulosic biomass (LCB) is sustainable. Due to its high specific surface area, porous structure, oxygen functional groups, and low cost, biochar has emerged as an alternate contender in catalysis. Various innovative advanced technologies were combined with biochar for effective wastewater treatment. This review examines the use of LCB for the synthesis of biochar along with its activation methods. It also elaborates on using advanced biochar-based technologies in wastewater treatment and the mechanism for forming oxidizing species. The research also highlights the use of machine learning in pollutant removal and identifies the obstacles of biochar-based catalysts in both real-time and cutting-edge technologies. Probable and restrictions for further exploration are discussed.