Copper is one of the most efficient and attractive metals for catalysis. In addition to their availability, low cost and limited toxicity, copper complexes are utilized to catalyze a broad variety of reactions, including examples involving radicals. For such reactions, organic halides are by far the most versatile and attractive substrates. Our contributions to the catalysis of radical reactions from organic halides with copper complexes are summarized in this account.

1 Introduction

2 Copper-Catalyzed Radical Cross-Coupling Reactions

3 Copper-Catalyzed Radical Reactions

4 Copper-Catalyzed Radical Carbonylative Cross-Coupling Reactions

5 Photoinduced, Copper-Catalyzed Radical Reactions

6 Conclusions and Outlook

铜是最有效和最具吸引力的催化金属之一。除了其可用性、低成本和有限的毒性之外，铜络合物还可用于催化多种反应，包括涉及自由基的反应。对于此类反应，有机卤化物是迄今为止最通用且最具吸引力的底物。本文总结了我们对有机卤化物与铜配合物的自由基反应催化的贡献。

1 简介

2 铜催化的自由基交叉偶联反应

3 铜催化的自由基反应

4 铜催化的自由基羰基交叉偶联反应

5 光诱导、铜催化的自由基反应

6 结论与展望