Nano Research ( IF 9.5 ) Pub Date : 2023-07-29 , DOI: 10.1007/s12274-023-5905-6
Chenchen Zhao , Dongbo Wang , Jiamu Cao , Zhi Zeng , Bingke Zhang , Jingwen Pan , Donghao Liu , Sihang Liu , Shujie Jiao , Tianyuan Chen , Gang Liu , Xuan Fang , Liancheng Zhao , Jinzhong Wang
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Broadband photodetectors with self-driven functions have attracted intensive scientific interest due to their low energy consumption and high optical gain. However, high-performance broadband self-driven photodetectors are still a significant challenge due to the complex fabrication processes, environmental toxicity, high production costs of traditional 3D semiconductor materials and sharply raised contact resistance, severe interfacial recombination of 2D materials and 2D/3D mixed dimension heterojunction. Here, 1D p-Te/2D n-Bi2Te3 heterojunctions are constructed by the simple and low-cost hydrothermal method. 1D p-Te/2D n-Bi2Te3 devices are applied in photoelectrochemical (PEC) photodetectors, with their high performance attributed to the good interfacial contacts reducing interface recombination. The device demonstrated a broad wavelength range (365–850 nm) with an/ph//dark as high as 377.45. The RiD*, and external quantum efficiency (EQE) values of the device were as high as 12.07 mA/W, 5.87 × 1010 Jones, and 41.05%, respectively, which were significantly better than the performance of the prepared Bi2Te3 and Te devices. A comparison of the freshly fabricated device and the device after 30 days showed that 1D p-Te/2D n-Bi2Te3 had excellent stability with only 18.08% decay of photocurrent. It is anticipated that this work will provide new emerging material for future design and preparation of a high-performance self-driven broadband photodetector.
中文翻译:

高效 1D p-Te/2D n-Bi2Te3 异质结自驱动宽带光电探测器
具有自驱动功能的宽带光电探测器由于其低能耗和高光学增益而引起了广泛的科学兴趣。然而,由于传统3D半导体材料的复杂制造工艺、环境毒性、高生产成本以及急剧升高的接触电阻、2D材料和2D/3D混合材料的严重界面复合,高性能宽带自驱动光电探测器仍然是一个重大挑战。维度异质结。这里,1D p-Te/2D n-Bi 2 Te 3异质结是通过简单且低成本的水热法构建的。1D p-Te/2D n-Bi 2 Te 3器件应用于光电化学(PEC)光电探测器,其高性能归因于良好的界面接触减少了界面复合。该器件具有宽波长范围 (365–850 nm),an/ ph / dark高达 377.45。器件的R i D * 和外量子效率(EQE)值分别高达12.07 mA/W、5.87 × 10 10 Jones和41.05%,明显优于所制备的Bi 2性能Te 3和 Te 器件。新制造的器件与 30 天后的器件的比较表明,1D p-Te/2D n-Bi 2 Te3具有优异的稳定性,光电流衰减仅为18.08%。预计这项工作将为未来高性能自驱动宽带光电探测器的设计和制备提供新兴材料。