2H-Phosphindole-Enabled Dearomatization and [4+2] Cycloaddition of (Hetero)Arenes,Chemistry - A European Journal

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2H-Phosphindole-Enabled Dearomatization and [4+2] Cycloaddition of (Hetero)Arenes
Chemistry - A European Journal ( IF 3.9 ) Pub Date : 2023-07-28 , DOI: 10.1002/chem.202301898
Haotian Luo ₁ , Junjian Wang ₁ , Rongqiang Tian ₁ , Zheng Duan ₁

Affiliation

Due to their unique electronic properties, the low-coordinate heavier main-group element species display high reactivity toward inert small molecules. Transient 2H-phosphinidole working as reactive phosphadiene undergoes phospha-Diels-Alder reaction with a wide range of non-activated aromatic carbocycles and heterocycles, providing simple but straightforward access to a range of polycyclic fused rings feature with bridgehead phosphorus.

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