Back-to-back cycloadditions in nature,Nature Chemistry

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Back-to-back cycloadditions in nature
Nature Chemistry ( IF 19.2 ) Pub Date : 2023-07-24 , DOI: 10.1038/s41557-023-01282-2
Richiro Ushimaru ₁ , Ikuro Abe ₁

Affiliation

Tandem cycloaddition reactions have significant applications in organic synthetic chemistry. Now, two enzymes are shown to catalyse tandem hetero-Diels–Alder reactions with a synergistic interplay between a calcium cofactor and N-glycan post-translational modifications during the biosynthesis of bistropolone-sesquiterpene secondary metabolites.

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