Journal of Cluster Science ( IF 2.7 ) Pub Date : 2023-07-21 , DOI: 10.1007/s10876-023-02478-9 Yu Song , Tingxuan Fu , Junbo Ning , Xiuyan Wang , Jiaxin Liu , Limin Chang
A new Pb(II) coordination polymer, namely, [Pb2(5-IPA)2(L)2]⋅H2O (1) (L = 1-(1H-imidazo[4,5-f][1,10]phenanthrolin-2-yl)naphthalen-2-ol and 5-H2IPA = 5-hydroxyisophthalic acid), has been synthesized under hydrothermal condition. The complex was characterized by single-crystal X-ray diffraction. 1 shows one-dimensional chain structure. The neighboring chains are extended into a two-dimensional supramolecular layer by π···π interactions. Further, two-dimensional layer structures are joined together by hydrogen-bonding interactions to yield a three-dimensional supramolecular structure. In addition, the thermogravimetric analysis and luminescent property of 1 have been investigated.
中文翻译:
基于1,10-菲咯啉衍生物和5-羟基间苯二甲酸的新型Pb(II)配位聚合物的合成、结构和表征
在水热条件下合成了一种新的Pb(II)配位聚合物,即[Pb 2 (5-IPA) 2 (L) 2 ]⋅H 2 O ( 1 ) (L = 1-(1H-咪唑[4,5-f][1,10]菲咯啉-2-基)萘-2-醇和5-H 2 IPA = 5-羟基间苯二甲酸) 。该配合物通过单晶X射线衍射进行了表征。图1显示一维链结构。相邻的链通过π·π相互作用延伸成二维超分子层。此外,二维层结构通过氢键相互作用连接在一起,产生三维超分子结构。此外,还对其热重分析和发光性能进行了研究。1已被调查。