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Electropolymerization of 5-amino-2-naphthalenesulfonic acid and their application as the electrode material for supercapacitors
Journal of Energy Storage ( IF 8.9 ) Pub Date : 2023-07-13 , DOI: 10.1016/j.est.2023.108308
Yu Tian , Yifan Yang , Yili Wu , Zixiang Zhou , Yvpei Li , Jinlian Wang , Shuling Liu , Chao Wang

Electropolymerization is a powerful tool in constructing conducting polymers that can be utilized as the electrode materials for flexible supercapacitors. The 5-amino-2-naphthalenesulfonic acid is electropolymerized at anodic potential on carbon cloth from aqueous perchloric acid solutions. The poly(5-amino-2-naphthalenesulfonic acid) coated carbon cloth electrodes (PANS/CC) are characterized, and are used as the electrode material for supercapacitors. The PANS/CC-40 exhibits the optimum charge storage performance, with the specific capacity of 85.5 mAh g−1 at 1 A g−1 charge-discharge current density in 1 M H2SO4. Specific capacities of 44.8 and 38.5 mAh g−1 are achieved for the PNAS/CC-40 in 1 M ZnSO4 and 1 M (NH4)2SO4, respectively, at 1 A g−1. Kinetic analyses show that the PNAS/CC-40 is a battery-type electrode material, and the surface-controlled processes contribute over 80 % of the stored charge. Evidences of cation (de)intercalation accompanying with the redox of amine/imine groups are given. A symmetric supercapacitor is assembled using two PNAS/CC-40 and the PVA/H2SO4 gel electrolyte, and it can deliver the energy density of 1.1 Wh kg−1 and the power density of 136.9 W kg−1 at 1 A g−1. The capacity retention of the symmetric supercapacitor is 88 % after 10,000 cycles at 5 A g−1.



中文翻译:

5-氨基-2-萘磺酸的电聚合及其作为超级电容器电极材料的应用

电聚合是构建导电聚合物的有力工具,可用作柔性超级电容器的电极材料。5-氨基-2-萘磺酸在阳极电位下由高氯酸水溶液在碳布上电聚合。对聚(5-氨基-2-萘磺酸)涂覆的碳布电极(PANS/CC)进行了表征,并将其用作超级电容器的电极材料。PANS/CC-40表现出最佳的电荷存储性能,在1 MH 2 SO 4中在1 A g -1充放电电流密度下比容量为85.5 mAh g -1。比容量为 44.8 和 38.5 mAh g −1PNAS/CC-40 分别在 1 M ZnSO 4和 1 M (NH 4 ) 2 SO 4中、在 1 A g -1下实现。动力学分析表明,PNAS/CC-40是一种电池型电极材料,表面控制过程贡献了80%以上的存储电荷。给出了伴随胺/亚胺基团氧化还原的阳离子(脱)插层的证据。使用两个PNAS/CC-40和PVA/H 2 SO 4凝胶电解质组装对称超级电容器,在1 A g下可提供1.1 Wh kg -1的能量密度和136.9 W kg -1的功率密度−1对称超级电容器在5 A g -1下循环10,000次后容量保持率为88% 。

更新日期:2023-07-13
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