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A Porous Crystalline Nitrone-Linked Covalent Organic Framework**
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2023-07-13 , DOI: 10.1002/anie.202307674
Daria Kurandina 1 , Banruo Huang 2 , Wentao Xu 1 , Nikita Hanikel 1 , Andrea Darù 3 , Gautam D Stroscio 3 , Kaiyu Wang 4 , Laura Gagliardi 3 , F Dean Toste 2 , Omar M Yaghi 4, 5
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2023-07-13 , DOI: 10.1002/anie.202307674
Daria Kurandina 1 , Banruo Huang 2 , Wentao Xu 1 , Nikita Hanikel 1 , Andrea Darù 3 , Gautam D Stroscio 3 , Kaiyu Wang 4 , Laura Gagliardi 3 , F Dean Toste 2 , Omar M Yaghi 4, 5
Affiliation
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A nitrone-linked covalent organic framework, COF-115, has been synthesized for the first time via polycondensation reaction. The sorption analyses of COF-115 revealed a porosity of 1387 m2/g, and a superior potential for atmospheric water harvesting and CO2 capture applications compared to their imine-based analogs. Finally, COF-115 was found to undergo a photochemical rearrangement to the corresponding amide-linked material.
中文翻译:
多孔结晶硝基连接的共价有机框架**
首次通过缩聚反应合成了硝酮连接的共价有机骨架COF-115。COF-115 的吸附分析显示其孔隙率为 1387 m 2 /g,与基于亚胺的类似物相比,其在大气水收集和 CO 2捕获应用方面具有优越的潜力。最后,发现 COF-115 发生光化学重排,形成相应的酰胺连接材料。
更新日期:2023-07-13
中文翻译:
![](https://scdn.x-mol.com/jcss/images/paperTranslation.png)
多孔结晶硝基连接的共价有机框架**
首次通过缩聚反应合成了硝酮连接的共价有机骨架COF-115。COF-115 的吸附分析显示其孔隙率为 1387 m 2 /g,与基于亚胺的类似物相比,其在大气水收集和 CO 2捕获应用方面具有优越的潜力。最后,发现 COF-115 发生光化学重排,形成相应的酰胺连接材料。