Solvent-free synthesis of magnesium phosphite-oxalates that show second-harmonic generation responses,Dalton Transactions

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Solvent-free synthesis of magnesium phosphite-oxalates that show second-harmonic generation responses
Dalton Transactions ( IF 3.5 ) Pub Date : 2023-07-07 , DOI: 10.1039/d3dt01885g
Lisiteng Luo _{1,

2} , Xuemei Wen ₁ , Juan Cheng ₁ , Jing Li ₁ , Hongmei Zeng ₁ , Guohong Zou ₁ , Zhien Lin ₁

Affiliation

Two new magnesium phosphite-oxalates were prepared under solvent-free conditions using different amines as structure-directing agents. They feature noncentrosymmetric structures with sql and dia topologies, respectively. The two compounds show moderate second-harmonic generation (SHG) responses under 1064 nm laser irradiation. Theoretical calculations were performed to reveal the origin of their SHG responses.

中文翻译：

无溶剂合成亚磷酸草酸镁，表现出二次谐波产生响应

使用不同的胺作为结构导向剂在无溶剂条件下制备了两种新的亚磷酸草酸镁。它们分别具有具有 sql 和 dia 拓扑的非中心对称结构。这两种化合物在 1064 nm 激光照射下表现出中等的二次谐波产生 (SHG) 响应。进行理论计算以揭示其二次谐波响应的起源。

更新日期：2023-07-12

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