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Programmable Amine Synthesis via Iterative Boron Homologation
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2023-07-07 , DOI: 10.1002/anie.202307118
Qiqiang Xie 1 , Rui Zhang 1 , Guangbin Dong 1
Affiliation  

Programmable amine synthesis is realized through sequential insertion of nitrogen and carbon atoms into boronate C−B bonds. This strategy is enabled by a new nitrenoid reagent, which allows for direct formation of aminoboranes from aryl or alkyl boronates via N-insertion.

中文翻译:

通过迭代硼同系化进行可编程胺合成

可编程胺合成是通过将氮和碳原子顺序插入硼酸CB键来实现的。这一策略是通过一种新的氮烯类试剂实现的,该试剂允许通过N-插入从芳基或烷基硼酸酯直接形成氨基硼烷。
更新日期:2023-07-07
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