Emergence of Ag as a Catalyst of Choice for Fluorination and Trifluoromethylation Reactions,ChemCatChem

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Emergence of Ag as a Catalyst of Choice for Fluorination and Trifluoromethylation Reactions
ChemCatChem ( IF 3.8 ) Pub Date : 2023-07-05 , DOI: 10.1002/cctc.202300677
Pradeep Kumar ₁ , Nikita Goel ₁ , Sunita Bhagat ₂

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The installation of F/CF₃ in the desired compounds is a very challenging task because of its electronegativity and small size. Several catalytic systems were developed for fluorination reaction, while silver catalyst emerged as the most likely used catalyst for these reactions. This Review showcases silver catalyzed fluorination and trifluoromethylation reactions for the synthesis of F/CF₃ containing aromatic, aliphatic and heterocyclic compounds. After reading this Review article the readers can develop a detailed understanding of the concept of silver metal catalyzed fluorination and trifluoromethylation reactions which can be explored for synthesizing molecules of biological interest.

中文翻译：

银作为氟化和三氟甲基化反应的首选催化剂的出现

由于其电负性和小尺寸，将 F/CF ₃安装在所需的化合物中是一项非常具有挑战性的任务。开发了几种用于氟化反应的催化系统，而银催化剂成为这些反应最有可能使用的催化剂。本综述展示了用于合成含有芳香族、脂肪族和杂环化合物的F/CF _{3的银催化氟化和三氟甲基化反应。}阅读这篇综述文章后，读者可以详细了解银金属催化的氟化和三氟甲基化反应的概念，这些反应可以探索合成具有生物学意义的分子。

更新日期：2023-07-05

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