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Synthesis of a Porous [14]Annulene Graphene Nanoribbon and a Porous [30]Annulene Graphene Nanosheet on Metal Surfaces
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2023-07-04 , DOI: 10.1002/anie.202306368 Tianchen Qin 1 , Dezhou Guo 2 , Juanjuan Xiong 1 , Xingyu Li 1 , Lei Hu 1 , Weishan Yang 1 , Zijie Chen 1 , Yulun Wu 1 , Honghe Ding 1 , Jun Hu 1 , Qian Xu 1 , Tao Wang 3 , Junfa Zhu 1
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2023-07-04 , DOI: 10.1002/anie.202306368 Tianchen Qin 1 , Dezhou Guo 2 , Juanjuan Xiong 1 , Xingyu Li 1 , Lei Hu 1 , Weishan Yang 1 , Zijie Chen 1 , Yulun Wu 1 , Honghe Ding 1 , Jun Hu 1 , Qian Xu 1 , Tao Wang 3 , Junfa Zhu 1
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Selective syntheses of one-dimensional graphene nanoribbons containing periodic nonplanar [14]annulene pores on Ag(111) and two-dimensional porous graphene nanosheet containing periodic nonplanar [30]annulene pores on Au(111) have been achieved. The reaction mechanisms were confirmed by a series of control experiments, and the appropriate thermodynamic and kinetic parameters for optimizing and tuning the reaction pathways were proposed.
中文翻译：
金属表面上多孔[14]环烯石墨烯纳米带和多孔[30]环烯石墨烯纳米片的合成
选择性合成了Ag(111)上含有周期性非平面[14]轮烯孔的一维石墨烯纳米带和Au(111)上含有周期性非平面[30]轮烯孔的二维多孔石墨烯纳米片。通过一系列控制实验证实了反应机理，并提出了用于优化和调整反应途径的适当热力学和动力学参数。
更新日期：2023-07-04
中文翻译：
金属表面上多孔[14]环烯石墨烯纳米带和多孔[30]环烯石墨烯纳米片的合成
选择性合成了Ag(111)上含有周期性非平面[14]轮烯孔的一维石墨烯纳米带和Au(111)上含有周期性非平面[30]轮烯孔的二维多孔石墨烯纳米片。通过一系列控制实验证实了反应机理，并提出了用于优化和调整反应途径的适当热力学和动力学参数。
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