High-Yielding, Versatile, and Practical [Rh(III)Cp*]-CatalyzedOrthoBromination and Iodination of Arenes,Journal of the American Chemical Society

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High-Yielding, Versatile, and Practical [Rh(III)Cp*]-CatalyzedOrthoBromination and Iodination of Arenes
Journal of the American Chemical Society ( IF 14.4 ) Pub Date : 2012-05-15 , DOI: 10.1021/ja302631j
Nils Schröder ₁ , Joanna Wencel-Delord ₁ , Frank Glorius ₁

Affiliation

We report a uniquely high-yielding, general, and practical ortho bromination and iodination reaction of different classes of aromatic compounds. This reaction occurs by Rh(III)-catalyzed C-H bond activation methodology and is therefore the first example of the application of this cationic catalyst for C-Br and C-I bond formation.

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