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二聚受体的构象及其效率超过18%的聚合物太阳能电池
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2023-06-28 , DOI: 10.1002/anie.202302888
Jingnan Wu 1, 2 , Zhaoheng Ling 3 , Leandro R Franco 4 , Sang Young Jeong 5 , Zewdneh Genene 1 , Josué Mena 1 , Si Chen 3 , Cailing Chen 6 , C Moyses Araujo 4, 7 , Cleber F N Marchiori 4 , Joost Kimpel 1 , Xiaoming Chang 3 , Furkan H Isikgor 3 , Qiaonan Chen 1 , Hendrik Faber 3 , Yu Han 6 , Frédéric Laquai 3 , Maojie Zhang 8 , Han Young Woo 5 , Donghong Yu 2 , Thomas D Anthopoulos 3 , Ergang Wang 1
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2023-06-28 , DOI: 10.1002/anie.202302888
Jingnan Wu 1, 2 , Zhaoheng Ling 3 , Leandro R Franco 4 , Sang Young Jeong 5 , Zewdneh Genene 1 , Josué Mena 1 , Si Chen 3 , Cailing Chen 6 , C Moyses Araujo 4, 7 , Cleber F N Marchiori 4 , Joost Kimpel 1 , Xiaoming Chang 3 , Furkan H Isikgor 3 , Qiaonan Chen 1 , Hendrik Faber 3 , Yu Han 6 , Frédéric Laquai 3 , Maojie Zhang 8 , Han Young Woo 5 , Donghong Yu 2 , Thomas D Anthopoulos 3 , Ergang Wang 1
Affiliation
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分别以硒酮和噻吩为桥合成了两种二聚体型受体DIBP3F-Se和DIBP3F-S。通过 NMR 和 DFT 模拟确定，两者均表现出 O 形构象，这是由分子内末端基团的强大 π-π 相互作用驱动的。PM6：DIBP3F-Se 基太阳能电池的效率为 18.09%。
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更新日期：2023-06-28
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