Twisted Diindeno-Fused Dibenzo[a,h]anthracene Derivatives and their Dianions,Angewandte Chemie International Edition

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Twisted Diindeno-Fused Dibenzo[a,h]anthracene Derivatives and their Dianions
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2023-06-26 , DOI: 10.1002/anie.202307750
Yanwei Gu _{1,

2} , Herdya S Torchon ₃ , Yikun Zhu ₃ , Zheng Wei ₃ , Dieter Schollmeyer ₄ , Manfred Wagner ₁ , Yong Ni ₅ , Zehua Wu ₁ , Hao Wu ₁ , Yazhou Zhou ₁ , Zijie Qiu ₁ , Marina A Petrukhina ₃ , Klaus Müllen _{1,

6}

Affiliation

Substituents of different sizes have been used to synthesize diindeno-fused dibenzo[a,h]anthracene derivatives with different degrees of non-planarity. The twisting of the neutral antiaromatic compounds led to them being endowed with chirality, as well as enhanced energy gaps with decreased diradical character. Furthermore, the doubly reduced species exhibited global aromaticity and decreased energy gaps with larger non-planarity.

中文翻译：

扭曲二茚并稠合二苯并[a,h]蒽衍生物及其二价阴离子

不同大小的取代基已被用来合成具有不同非平面性程度的二茚并稠合二苯并[ a , h ]蒽衍生物。中性反芳香族化合物的扭曲导致它们被赋予手性，以及增强的能隙和减少的双自由基特征。此外，双重还原的物质表现出整体芳香性，并且能隙减小，非平面性更大。

更新日期：2023-06-26

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