Abstract

1-(2-Aminoethyl)-3,5-diallyl-1,3,5-triazinane-2,4,6-trione reacted with phenyl isocyanate and hexa­methylene diisocyanate to give previously unknown isocyanurates and bis-isocyanurates containing one or two urea fragments, respectively. The reaction of 3,5-diallyl-1-(2-hydroxyethyl)-1,3,5-triazinane-2,4,6-trione with phenyl isocyanate afforded 2-(3,5-diallyl-2,4,6-trioxo-1,3,5-triazinan-1-yl)ethyl phenylcarbamate, and the alkylation of 3,5-diallyl-1,3,5-triazinane-2,4,6-trione sodium salt with bis(2-chloroethyl) hexane-1,6-diyldi­carbamate produced bis[2-(3,5-diallyl-2,4,6-trioxo-1,3,5-triazinan-1-yl)ethyl] hexane-1,6-diyldicarbamate. Physical and spectroscopic properties of the synthesized isocyanurates and bis-isocyanurates were studied.

中文翻译：

---

N-[2-(3,5-二烯丙基-2,4,6-三氧代-1,3,5-三嗪-1-基)乙基]脲和-氨基甲酸酯的合成

摘要

1-(2-氨基乙基)-3,5-二烯丙基-1,3,5-三嗪烷-2,4,6-三酮与异氰酸苯酯和六亚甲基二异氰酸酯反应，得到以前未知的含有一种或两种脲的异氰脲酸酯和双异氰脲酸酯片段，分别。3,5-二烯丙基-1-(2-羟乙基)-1,3,5-三嗪烷-2,4,6-三酮与异氰酸苯酯反应得到2-(3,5-二烯丙基-2,4,6 -三氧代-1,3,5-三嗪烷-1-基)乙基苯基氨基甲酸酯，以及3,5-二烯丙基-1,3,5-三嗪烷-2,4,6-三酮钠盐与双(2-氯乙基）己烷-1,6-二氨基甲酸酯生成双[2-(3,5-二烯丙基-2,4,6-三氧代-1,3,5-三嗪-1-基)乙基]己烷-1,6-二氨基甲酸酯。研究了合成的异氰脲酸酯和双异氰脲酸酯的物理和光谱性质。