Matter ( IF 17.3 ) Pub Date : 2023-06-23 , DOI: 10.1016/j.matt.2023.05.043 Yang Liu , Fushan Li , Wei Huang
The hybrid perovskite family characterized by exciting optoelectronic properties and chemical/physical versatilities holds potential for photonic applications. In addition to materials, the micro-/nanoarchitectures are critical to photonic-related properties (reflection/scattering/trapping/extraction/resonance/modulation) and spatially patterned arrays by photon-matter-structure interactions. The abundant processing strategies—covering in situ crystallization, the pre-synthesized nanocrystals (NCs), and vapor deposition—evolve kaleidoscopic perovskite architectures and photonic properties resulting from extensive experimental and theoretical efforts in various fields. Here, we review the perovskite micro-/nanoarchitectures with regard to photonic applications. We start with the perovskite materials, structure, and related optical dimensions, then systematically illustrate the top-down and bottom-up micro-/nanopatterning techniques including direct generation, indirect replication, and others to take full use of perovskite’s unique processing advantages and optoelectronic properties. We discuss the intrinsic material emission and photo-matter-structure interaction originating from micro-/nanoarchitecture to promote patterning/structuring photon-emitting, -sensing, and -modulating applications.
中文翻译:
用于光子应用的钙钛矿微/纳米结构
杂化钙钛矿家族具有令人兴奋的光电特性和化学/物理多功能性,具有光子应用的潜力。除了材料之外,微/纳米结构对于光子相关特性(反射/散射/捕获/提取/共振/调制)和通过光子-物质-结构相互作用形成的空间图案阵列也至关重要。丰富的加工策略——原位覆盖结晶、预合成的纳米晶体(NC)和气相沉积——通过各个领域的广泛实验和理论努力,演变出万花筒般的钙钛矿结构和光子特性。在这里,我们回顾了钙钛矿微/纳米结构在光子应用方面的应用。我们从钙钛矿材料、结构和相关光学尺寸入手,系统地阐述了自上而下和自下而上的直接生成、间接复制等微纳米图案化技术,以充分利用钙钛矿独特的加工优势和光电特性。特性。我们讨论源自微/纳米结构的本征材料发射和光-物质-结构相互作用,以促进图案化/结构化光子发射、传感、