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One-step synthesis of novel carbon dots through cross amide formation of benzene-1,3,5-triamine and trimethyl 1,3,5-benzenetricarboxylate for fluorescence Hg2+ detection
Dyes and Pigments ( IF 4.1 ) Pub Date : 2023-06-16 , DOI: 10.1016/j.dyepig.2023.111485
Shaofang Ma , Zihan Zhu , Jianfei Xu , Jing Wang , Xinjing Tang , Wei Bian

Herein, we rationally designed and synthesized novel green-emitting fluorescent carbon dots (CDs) through cross amide formation of two precursors, benzene-1,3,5-triamine trihydrochloride and trimethyl 1,3,5-benzenetricarboxylate, under hydrothermal treatment. The average particle size of the CDs was ∼2.7 nm with graphitic carbon structures. The obtained CDs showed good photoluminescent properties with a quantum yield of up to 11.2%. The carbon dots showed good fluorescence sensitivity and selectivity for Hg2+, and the LOD and LOQ values were 17.5 pM and 58.3 pM in the range of 0.1–0.8 μM, which could be successfully applied to Hg2+ detection in real water samples as well as intracellular Hg2+ fluorescence detection.



中文翻译:

通过苯-1,3,5-三胺和1,3,5-苯三甲酸三甲酯的交叉酰胺形成一步合成新型碳点用于荧光Hg2+检测

在此,我们通过两种前体苯-1,3,5-三胺三盐酸盐和1,3,5-苯三甲酸三甲酯在水热处理下形成交叉酰胺,合理设计并合成了新型绿光荧光碳点(CD)。CD 的平均粒径为 ∼2.7 nm,具有石墨碳结构。所得CD表现出良好的光致发光性能,量子产率高达11.2%。碳点对Hg 2+表现出良好的荧光灵敏度和选择性,在0.1~0.8 μM范围内LOD和LOQ值分别为17.5 pM和58.3 pM,可成功应用于实际水样中Hg 2+ 的检测。以及细胞内Hg 2+荧光检测。

更新日期:2023-06-20
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