Electrocatalytic Urea Synthesis with 63.5 % Faradaic Efficiency and 100 % N-Selectivity via One-step C−N coupling,Angewandte Chemie International Edition

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Electrocatalytic Urea Synthesis with 63.5 % Faradaic Efficiency and 100 % N-Selectivity via One-step C−N coupling
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2023-06-20 , DOI: 10.1002/anie.202305447
Xiaoran Zhang _{1,

2} , Xiaorong Zhu _{3,

4} , Shuowen Bo ₅ , Chen Chen ₁ , Kai Cheng ₆ , Jianyun Zheng ₁ , Shuang Li ₁ , Xiaojin Tu ₁ , Wei Chen ₁ , Chao Xie ₁ , Xiaoxiao Wei ₁ , Dongdong Wang ₁ , Yingying Liu ₁ , Pinsong Chen ₂ , San Ping Jiang _{2,

7} , Yafei Li ₄ , Qinghua Liu ₅ , Conggang Li ₆ , Shuangyin Wang ₁

Affiliation

The electrocatalytic C−N coupling of carbon dioxide and nitrogen is a sustainable and promising alternative for urea synthesis. Here we demonstrate that the one-step C−N coupling via direct insertion of CO into N₂ molecules is the intrinsic cause for the ∼100 % N-selectivity to urea.

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