Pd-Enriched-Core/Pt-Enriched-Shell High-Entropy Alloy with Face-Centred Cubic Structure for C1 and C2 Alcohol Oxidation,Angewandte Chemie International Edition

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Pd-Enriched-Core/Pt-Enriched-Shell High-Entropy Alloy with Face-Centred Cubic Structure for C1 and C2 Alcohol Oxidation
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2023-06-06 , DOI: 10.1002/anie.202304510
Xianzhuo Lao ₁ , Xuejiang Liao ₁ , Chen Chen ₁ , Jiasheng Wang ₁ , Likang Yang ₁ , Ze Li ₁ , Jun-Wei Ma ₂ , Aiping Fu ₃ , Hongtao Gao ₂ , Peizhi Guo ₁

Affiliation

A facile low-temperature synthesis method at atmospheric pressure is employed to synthesize nanoparticles (NPs) with Pd-enriched high-entropy alloy (HEA) core and Pt-enriched HEA shell in a pure phase of face-centred cubic structure. The obtained PdAgSn/PtBi HEA NPs exhibit 2874 and 3386 mA mg_(Pd+Pt)⁻¹ for methanol oxidation reaction (MOR) and ethanol oxidation reaction (EOR), respectively.

中文翻译：

用于 C1 和 C2 醇氧化的面心立方结构富 Pd 核/富 Pt 壳高熵合金

采用常压下简便的低温合成方法，在面心立方结构的纯相中合成了具有富 Pd 高熵合金 (HEA) 核和富 Pt HEA 壳的纳米颗粒 (NP)。所获得的PdAgSn/PtBi HEA NPs对于甲醇氧化反应(MOR)和乙醇氧化反应(EOR)分别表现出2874和3386 mA mg _(Pd+Pt)^{-1 。}

更新日期：2023-06-06

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