Additive-Free Transfer Hydrogenative Direct Asymmetric Reductive Amination Using a Chiral Pyridine-Derived Half-Sandwich Catalyst,Angewandte Chemie International Edition

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Additive-Free Transfer Hydrogenative Direct Asymmetric Reductive Amination Using a Chiral Pyridine-Derived Half-Sandwich Catalyst
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2023-06-01 , DOI: 10.1002/anie.202303709
Yuan Gao _{1,

2} , Zhijun Wang ₃ , Xinyu Zhang ₃ , Min Zhao ₁ , Shuai Zhang ₁ , Chao Wang ₄ , Liang Xu ₃ , Pengfei Li _{1,

2,

5}

Affiliation

An inherently challenging enantioselective direct reductive amination reaction under mild and operationally simple transfer hydrogenative conditions was developed using a rationally designed, chiral pyridine-derived half-sandwich iridium catalyst. The reaction was compatible with various functional groups and coordinative heterocycles.

中文翻译：