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Development of Composite Inorganic Building Blocks for MOFs
Journal of the American Chemical Society ( IF 14.4 ) Pub Date : 2012-02-27 , DOI: 10.1021/ja2118255 Shou-Tian Zheng 1 , Tao Wu , Chengtsung Chou , Addis Fuhr , Pingyun Feng , Xianhui Bu
Journal of the American Chemical Society ( IF 14.4 ) Pub Date : 2012-02-27 , DOI: 10.1021/ja2118255 Shou-Tian Zheng 1 , Tao Wu , Chengtsung Chou , Addis Fuhr , Pingyun Feng , Xianhui Bu
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A general direction for diversifying metal-organic frameworks (MOFs) is demonstrated by the synthesis of composite inorganic clusters between indium and s-, d-, and f-block elements. These previously unknown heterometallic clusters, with various nuclearity, geometry, charge, and metal-to-metal ratios, significantly expand the pool of inorganic building blocks that are highly effective for the construction of porous MOFs with high gas uptake capacity.
中文翻译：
MOF 复合无机砌块的开发
金属有机框架（MOF）多样化的总体方向是通过合成铟与 s、d 和 f 块元素之间的复合无机簇来证明的。这些以前未知的异金属簇具有不同的核数、几何形状、电荷和金属与金属的比率，显着扩展了无机构建块的库，这些构建块对于构建具有高气体吸收能力的多孔 MOF 非常有效。
更新日期：2012-02-27
中文翻译：
MOF 复合无机砌块的开发
金属有机框架（MOF）多样化的总体方向是通过合成铟与 s、d 和 f 块元素之间的复合无机簇来证明的。这些以前未知的异金属簇具有不同的核数、几何形状、电荷和金属与金属的比率，显着扩展了无机构建块的库，这些构建块对于构建具有高气体吸收能力的多孔 MOF 非常有效。
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