Atroposelective Synthesis of Axially Chiral Styrenes by Platinum- Catalyzed Stereoselective Hydrosilylation of Internal Alkynes,Angewandte Chemie International Edition

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Atroposelective Synthesis of Axially Chiral Styrenes by Platinum- Catalyzed Stereoselective Hydrosilylation of Internal Alkynes
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2023-05-25 , DOI: 10.1002/anie.202305518
Qimin Wu ₁ , Qi Zhang ₁ , Shuxin Yin ₁ , Aijun Lin ₁ , Shang Gao ₁ , Hequan Yao ₁

Affiliation

A platinum-catalyzed atroposelective hydrosilylation of unactivated internal alkynes has been developed. Various styrene-type atropisomers with open-chained olefins were obtained with high stereo- and enantioselectivity.

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