Alkane Solvent-Derived Acylation Reaction Driven by Electric Fields,Journal of the American Chemical Society

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Alkane Solvent-Derived Acylation Reaction Driven by Electric Fields
Journal of the American Chemical Society ( IF 14.4 ) Pub Date : 2023-05-25 , DOI: 10.1021/jacs.3c02064
Xiye Wang ₁ , Boyuan Zhang ₂ , Brandon Fowler ₁ , Latha Venkataraman _{1,

2} , Tomislav Rovis ₁

Affiliation

Electric field acceleration of alkyl hydroperoxide activation to acylate amines in the scanning tunneling microscope-based break-junction is reported. Alkyl hydroperoxide mixtures, generated from hydrocarbon autoxidation in air, were found to be competent reagents for the functionalization of gold surfaces. Intermolecular coupling on the surface in the presence of amines was observed, yielding normal alkylamides. This novel mode of alkyl hydroperoxide activation to generate acylium equivalents was found to be responsive to the magnitude of the bias in the break junction, indicating an electric field influence on this novel reactivity.

中文翻译：

电场驱动的烷烃溶剂衍生酰化反应

报道了在基于扫描隧道显微镜的断裂结中烷基氢过氧化物活化酰化胺的电场加速。烃类在空气中自动氧化产生的烷基氢过氧化物混合物被发现是金表面功能化的有效试剂。观察到在存在胺的情况下表面上的分子间偶联，产生正常的烷基酰胺。发现这种新的烷基氢过氧化物活化模式产生酰基当量对断裂连接处的偏压大小有反应，表明电场对这种新反应性的影响。

更新日期：2023-05-25

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