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Recent advances in atomically precise metal nanoclusters for electrocatalytic applications
Inorganic Chemistry Frontiers ( IF 6.1 ) Pub Date : 2023-05-25 , DOI: 10.1039/d3qi00656e Xinhua Yuan 1 , Manzhou Zhu 1
Inorganic Chemistry Frontiers ( IF 6.1 ) Pub Date : 2023-05-25 , DOI: 10.1039/d3qi00656e Xinhua Yuan 1 , Manzhou Zhu 1
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In comparison with metal nanoparticles, atomically precise nanoclusters provide a more advantageous platform for investigating the actual active sites and reaction mechanisms of electrocatalysis at the atomic or molecular scale. Until now, many efficient nanocluster-based electrocatalysts have been investigated for numerous electrocatalytic applications. In this review, we summarize recent advances in atomically precise metal nanoclusters for electrocatalytic applications, including the hydrogen evolution reaction, electrochemical synthesis of ammonia, electrochemical CO2 reduction reaction, fuel cell reaction, and pollutant degradation reaction. In particular, the crucial factors affecting the electrocatalytic performance of metal nanoclusters are discussed and concluded in detail, such as the composition of the metal core, the charge state of metal atoms, the type of protection ligand, precise structure, and different substrates. Simultaneously, suggestions for improvements and future perspectives of atomically precise metal nanoclusters for electrochemical applications are highlighted in the end. This review is intended to offer a deeper comprehension of the advantages of atomically precise metal nanoclusters and to form a basis for their more extensive utilization in electrocatalysis.
中文翻译：
用于电催化应用的原子精确金属纳米团簇的最新进展
与金属纳米粒子相比，原子级精确的纳米团簇为在原子或分子尺度上研究电催化的实际活性位点和反应机制提供了一个更有优势的平台。到目前为止，已经研究了许多基于纳米团簇的高效电催化剂用于许多电催化应用。在这篇综述中，我们总结了用于电催化应用的原子精确金属纳米团簇的最新进展，包括析氢反应、氨的电化学合成、电化学 CO 2还原反应、燃料电池反应、污染物降解反应。特别地，详细讨论和总结了影响金属纳米团簇电催化性能的关键因素，例如金属核的组成、金属原子的电荷状态、保护配体的类型、精确的结构和不同的底物。同时，最后强调了用于电化学应用的原子精确金属纳米团簇的改进建议和未来前景。这篇综述旨在更深入地理解原子精确金属纳米团簇的优势，并为其在电催化中更广泛的应用奠定基础。
更新日期：2023-05-25
中文翻译：
用于电催化应用的原子精确金属纳米团簇的最新进展
与金属纳米粒子相比，原子级精确的纳米团簇为在原子或分子尺度上研究电催化的实际活性位点和反应机制提供了一个更有优势的平台。到目前为止，已经研究了许多基于纳米团簇的高效电催化剂用于许多电催化应用。在这篇综述中，我们总结了用于电催化应用的原子精确金属纳米团簇的最新进展，包括析氢反应、氨的电化学合成、电化学 CO 2还原反应、燃料电池反应、污染物降解反应。特别地，详细讨论和总结了影响金属纳米团簇电催化性能的关键因素，例如金属核的组成、金属原子的电荷状态、保护配体的类型、精确的结构和不同的底物。同时，最后强调了用于电化学应用的原子精确金属纳米团簇的改进建议和未来前景。这篇综述旨在更深入地理解原子精确金属纳米团簇的优势，并为其在电催化中更广泛的应用奠定基础。
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