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Transmembrane fluoride anion transport by meso-3,5-bis(trifluoromethyl)phenyl picket calix[4]pyrrole
Chemical Communications ( IF 4.3 ) Pub Date : 2023-05-19 , DOI: 10.1039/d3cc02032k Ashoke Kumar Patra 1 , Soumya Srimayee 2 , Dibakar Halder 1 , Anik Roy 1 , Souvik Mukherjee 1 , Somenath Kundu 3 , Maidul Hossain 3 , Rajat Saha 4 , Chang-Hee Lee 5 , Debasis Manna 2 , Indrajit Saha 1
Chemical Communications ( IF 4.3 ) Pub Date : 2023-05-19 , DOI: 10.1039/d3cc02032k Ashoke Kumar Patra 1 , Soumya Srimayee 2 , Dibakar Halder 1 , Anik Roy 1 , Souvik Mukherjee 1 , Somenath Kundu 3 , Maidul Hossain 3 , Rajat Saha 4 , Chang-Hee Lee 5 , Debasis Manna 2 , Indrajit Saha 1
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Meso-3,5-bis(trifluoromethyl)phenyl picket calix[4]pyrrole 1 displays excellent fluoride anion transport activity across artificial lipid bilayers showing EC50 = 2.15 μM (at 450 s in EYPC vesicle) with high fluoride over chloride ion selectivity. The high fluoride selectivity of 1 was ascribed to the formation of a sandwich type π-anion-π interaction complex.
中文翻译:
meso-3,5-双(三氟甲基)苯基尖桩杯[4]吡咯跨膜氟阴离子转运
Meso -3,5-bis(trifluoromethyl)phenyl picket calix[4]pyrrole 1在人工脂质双层中表现出优异的氟阴离子转运活性,显示 EC 50 = 2.15 μM(在 EYPC 囊泡中 450 秒),氟离子对氯离子的选择性高。1的高氟化物选择性归因于夹心型 π-阴离子-π 相互作用复合物的形成。
更新日期:2023-05-19
中文翻译:
![](https://scdn.x-mol.com/jcss/images/paperTranslation.png)
meso-3,5-双(三氟甲基)苯基尖桩杯[4]吡咯跨膜氟阴离子转运
Meso -3,5-bis(trifluoromethyl)phenyl picket calix[4]pyrrole 1在人工脂质双层中表现出优异的氟阴离子转运活性,显示 EC 50 = 2.15 μM(在 EYPC 囊泡中 450 秒),氟离子对氯离子的选择性高。1的高氟化物选择性归因于夹心型 π-阴离子-π 相互作用复合物的形成。