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Nickel-Catalyzed Electrochemical Cyclizative Carboxylation of Alkene-Tethered Carbamoyl Chlorides with Carbon Dioxide
Synthesis ( IF 2.2 ) Pub Date : 2023-05-16 , DOI: 10.1055/s-0041-1738439 Lin-Lin Wang , Xiao-Fei Liu , Wen-Zhen Zhang , He Wang , Li Tao , Jian Huang , Wei-Min Ren , Xiao-Bing Lu
中文翻译:
镍催化烯烃系氨基甲酰氯与二氧化碳的电化学环化羧化
更新日期:2023-05-17
Synthesis ( IF 2.2 ) Pub Date : 2023-05-16 , DOI: 10.1055/s-0041-1738439 Lin-Lin Wang , Xiao-Fei Liu , Wen-Zhen Zhang , He Wang , Li Tao , Jian Huang , Wei-Min Ren , Xiao-Bing Lu
Nickel-catalyzed electrochemical cyclizative carboxylation of alkene-tethered carbamoyl chlorides with atmospheric carbon dioxide in an undivided cell under simple constant current conditions is reported. This reaction is conducted with high efficiency under mild conditions, providing a convenient and green access to valuable 2-oxoindolin-3-ylacetic acids and 2-oxo-tetrahydroquinoline-4-carboxylic acids.
中文翻译:
镍催化烯烃系氨基甲酰氯与二氧化碳的电化学环化羧化
报道了在简单的恒定电流条件下,在未分隔的电池中,镍催化的烯烃系氨基甲酰氯与大气二氧化碳的电化学环化羧化反应。该反应在温和条件下高效进行,为获得有价值的 2-oxoindolin-3-ylacetic acids 和 2-oxo-tetrahydroquinoline-4-carboxylic acids 提供了方便和绿色的途径。