Photo- and Electrochemical Cobalt Catalysed Hydrogen Atom Transfer for the Hydrofunctionalisation of Alkenes,Angewandte Chemie International Edition

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Photo- and Electrochemical Cobalt Catalysed Hydrogen Atom Transfer for the Hydrofunctionalisation of Alkenes
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2023-05-15 , DOI: 10.1002/anie.202304882
Samikshan Jana ₁ , Victor J Mayerhofer ₁ , Christopher J Teskey ₁

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Cobalt catalysis is an effective method for transferring a hydrogen atom to olefins, forming the corresponding branched alkyl radicals and leading to Markovnikov hydrofunctionalisation products. The recent merger of this area with photo- and electro-catalysis has introduced new reactivity, milder reaction conditions and improved functional group tolerance. This review summarises these advances and provides an outlook for future developments.

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