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Reactions of highly electrophilic 6,8-dinitro[1,2,4]triazolo[1,5-a]pyridines with C-nucleophiles
Russian Chemical Bulletin ( IF 1.7 ) Pub Date : 2023-05-11 , DOI: 10.1007/s11172-023-3860-6 M. A. Bastrakov , V. G. Nadykta , A. K. Fedorenko , A. M. Starosotnikov
中文翻译:
高亲电性 6,8-二硝基 [1,2,4] 三唑并 [1,5-a] 吡啶与 C-亲核试剂的反应
更新日期:2023-05-12
Russian Chemical Bulletin ( IF 1.7 ) Pub Date : 2023-05-11 , DOI: 10.1007/s11172-023-3860-6 M. A. Bastrakov , V. G. Nadykta , A. K. Fedorenko , A. M. Starosotnikov
Reactions of 2-R-6,8-dinitro[1,2,4]triazolo[1,5-a]pyridines with indoles and 1,3-dicarbonyl compounds were studied. It was found that stable products of nucleophilic addition to the pyridine ring were formed under mild conditions in the absence of a base. The new derivatives of 1,5-dihydro[1,2,4]triazolo[1,5-a]pyridine were synthesized in up to 96% yield.
中文翻译:
高亲电性 6,8-二硝基 [1,2,4] 三唑并 [1,5-a] 吡啶与 C-亲核试剂的反应
研究了2-R-6,8-二硝基 [1,2,4] 三唑并 [1,5- a ] 吡啶与吲哚和 1,3-二羰基化合物的反应。发现在没有碱的情况下,在温和条件下形成稳定的吡啶环亲核加成产物。合成了 1,5-二氢[1,2,4] 三唑并[1,5- a ] 吡啶的新衍生物,产率高达 96%。