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Ligand-directed structure evolution from a titanium-oxo cluster to coordination capsule and one-dimensional coordination polymer based on {Ti3O} units
New Journal of Chemistry ( IF 2.7 ) Pub Date : 2023-05-11 , DOI: 10.1039/d3nj01172k
Min Meng 1 , Lingrong Liao 2 , Qi Zheng 2 , Weimin Xuan 1
Affiliation  

By modulating the geometry and size of the ligand and using phosphite as a bridging linker, {Ti33-O)} can be assembled into a discrete {Ti6} cluster, coordination capsule {Ti18Cu3} and one-dimensional coordination polymer {Ti6}n.

中文翻译:

从钛-氧簇到配位胶囊和基于 {Ti3O} 单元的一维配位聚合物的配体定向结构演变

通过调节配体的几何形状和大小,并使用亚磷酸盐作为桥接连接体,{Ti 33 -O)} 可以组装成离散的 {Ti 6 } 簇、配位胶囊 {Ti 18 Cu 3 } 和单-维配位聚合物{Ti 6 } n
更新日期:2023-05-11
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