Crystal Structure and Photochromic Properties of Two Complexes based on 1-(4-carboxybenzyl)-4,4′-bipyridinium Ligand,ChemistrySelect

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Crystal Structure and Photochromic Properties of Two Complexes based on 1-(4-carboxybenzyl)-4,4′-bipyridinium Ligand
ChemistrySelect ( IF 1.9 ) Pub Date : 2023-05-08 , DOI: 10.1002/slct.202300478
Fengyi Yang ₁ , Na Liu ₁ , Jiali Chen ₁ , Jinjian Liu _{1,

2}

Affiliation

Two novel complexes {[Zn(BCbpy)(m-BDC)(H₂O)] ⋅ 2H₂O}_n (1) and [Co(H₂O)₆]_0.5[Co_0.5(BCbpy)(H₂O)₂](m-BDC) ⋅ 3H₂O ⋅ DMF (2) based on BCbpy have been got, which both exhibit photochromism. Interestingly, 1 can be dissolved in ethanol solution and deposited on filter paper, applied to a printing medium without ink.

中文翻译：

基于 1-(4-羧基苄基)-4,4'-联吡啶配体的两种配合物的晶体结构和光致变色性能

两种新型配合物 {[Zn(BCbpy)( m -BDC)(H ₂ O)] ⋅ 2H ₂ O} _n ( 1 ) 和 [Co(H ₂ O) ₆ ] _0.5 [Co _0.5 (BCbpy)(H ₂ O ) ₂ ]( m -BDC) ⋅ 3H ₂ O ⋅ DMF ( 2 ) 基于BCbpy得到，均表现出光致变色。有趣的是，1可以溶解在乙醇溶液中并沉积在滤纸上，应用于无墨水的印刷介质。

更新日期：2023-05-10

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