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Y-Shaped D-A Type Thioxanthone Derivatives: Mechano-Induced Thermally Activated Delayed Fluorescence and High-Contrast Mechano-Responsive Luminescence
Chemistry - A European Journal ( IF 3.9 ) Pub Date : 2023-05-07 , DOI: 10.1002/chem.202300867
Yingxiao Mu 1, 2, 3 , Liyun Liao 2 , Wenlang Li 1 , Zhiyong Yang 1, 4 , Yi Zhang 1, 4 , Yanping Huo 2 , Zhenguo Chi 1, 3
Affiliation  

Y-shaped D-A type molecules possessed two independent ICT states inside, resulted from the two independent D−A conjugation from their small donor arms to the acceptor. As their two D−A torsion angles are very sensitive to aggregated states, they showed interesting mechano-induced TADF and high-contrast MRL properties.

中文翻译:

Y 型 DA 型噻吨酮衍生物:机械诱导热激活延迟荧光和高对比度机械响应发光

Y形DA型分子内部具有两个独立的ICT状态,这是由它们的小供体臂与受体的两个独立的D−A缀合产生的。由于它们的两个 D−A 扭转角对聚合态非常敏感,因此它们表现出有趣的机械诱导 TADF 和高对比度 MRL 特性。
更新日期:2023-05-07
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