当前位置: X-MOL 学术Colloids Surf. A Physicochem. Eng. Aspects › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
MOF-derived In2O3 nanotubes modified by r-GO for highly sensitive NOx detection at room temperature
Colloids and Surfaces A: Physicochemical and Engineering Aspects ( IF 4.9 ) Pub Date : 2023-05-08 , DOI: 10.1016/j.colsurfa.2023.131609
Jiongjiang Liu , Yuanyuan Liu , Qingjiang Pan , Guo Zhang

MIL-68(In)-derived hollow tubular In2O3 compound with reduced graphite oxide (r-GO) is synthesized by solvothermal method. The In2O3/r-GO gas sensor is utilized for NOx detection at room temperature. Notably, the In2O3/r-GO achieved ultra-high response performance (2761) and fast response/recovery time (210/36s) for 100 ppm NOx than In2O3 (19.3, 345/200s). Meanwhile, the In2O3/r-GO sensor exhibits good selectivity and repeatability for NOx. The mechanism of NOx adsorption onto the material surface is investigated by DRIFT. The synergistic effect of In2O3 and r-GO is responsible for the improved gas-sensitive performance. The high surface area of In2O3/r-GO composites can provide more adsorption sites for the target gas. The excellent electron transport capability of r-GO nanosheets can reduce the response/recovery time. In addition, the formed heterogeneous structure increases the chemisorbed oxygen content, which promotes the response value. Therefore, In2O3/r-GO gas sensors show promising applications for monitoring NOx.



中文翻译:

r-GO 修饰的 MOF 衍生 In2O3 纳米管用于室温下高灵敏度的 NOx 检测

采用溶剂热法合成了MIL-68(In) 衍生的中空管状 In 2 O 3化合物与还原氧化石墨 (r-GO)。In 2 O 3 /r-GO气体传感器用于室温下的NO x检测。值得注意的是,与 In 2 O 3 (19.3, 345/200s)相比,In 2 O 3 /r-GO 对于 100 ppm NO x实现了超高响应性能 (2761) 和快速响应/恢复时间 (210/36s)。同时,In 2 O 3 /r-GO传感器对NO x表现出良好的选择性和重复性。NOx的作用机理通过 DRIFT 研究材料表面的吸附。In 2 O 3和r-GO的协同作用是提高气敏性能的原因。In 2 O 3 /r-GO复合材料的高表面积可以为目标气体提供更多的吸附位点。r-GO 纳米片出色的电子传输能力可以减少响应/恢复时间。此外,形成的异质结构增加了化学吸附氧含量,从而提高了响应值。因此,In 2 O 3 /r-GO 气体传感器显示出用于监测 NO x的有前途的应用。

更新日期:2023-05-10
down
wechat
bug