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Ascendancy of Cr2O3 on morphology, spectroscopic and dielectric properties of GeO2–Li2O–P2O5–MgO glasses
Materials Chemistry and Physics ( IF 4.3 ) Pub Date : 2023-05-07 , DOI: 10.1016/j.matchemphys.2023.127889
N. Sreeram , S. Yusub , A. Ramesh Babu , M. Venkateswarlu , G. Krishna Priya , V. Aruna , Ravindranadh Koutavarapu

The dielectric, physical, and optical properties of 5GeO2–30Li2O–55P2O5–(10-x)MgO–xCr2O3 (x varies from 0 to 0.9 mol%) glasses were investigated. The specimens were synthesized using melt quenching and heat treatment techniques. The non-crystalline behavior of the specimens was analyzed by X-ray diffraction. The physical parameters of these glasses were also determined. These parameters indicate the compact nature of the glasses. The optical absorption spectra of the specimens show bands corresponding to Cr3+ ions. The optical band gap (Eg) and Urbach energy (ΔE) of glasses were evaluated. Fourier-transform infrared and Raman spectra showed typical bands related to the phosphate species and supported the structural changes in the glasses. The emission and electron spin resonance (ESR) spectra confirmed the presence of chromium ions (Cr3+ state) in the glasses. An increase in the intensity of the ESR resonance signals and emission bands suggested an increase in the number of chromium ions. The dielectric parameters of the samples are also determined.



中文翻译:

Cr2O3 对 GeO2–Li2O–P2O5–MgO 玻璃形貌、光谱和介电性能的影响

研究了5GeO 2 –30Li 2 O–55P 2 O 5 –(10-x)MgO–xCr 2 O 3 (x 从 0 到 0.9 mol%)玻璃的介电、物理和光学特性。使用熔体淬火和热处理技术合成样品。通过 X 射线衍射分析样品的非结晶行为。还确定了这些玻璃的物理参数。这些参数表明眼镜的紧凑性。样品的光吸收光谱显示对应于 Cr 3+离子的谱带。光学带隙(E g) 和玻璃的 Urbach 能量 (ΔE) 进行了评估。傅立叶变换红外和拉曼光谱显示出与磷酸盐种类相关的典型波段,并支持玻璃中的结构变化。发射和电子自旋共振 (ESR) 光谱证实玻璃中存在铬离子(Cr3+ESR 共振信号和发射带强度的增加表明铬离子数量增加。样品的介电参数也被确定。

更新日期:2023-05-09
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