Electrolyte regulation plays its critical role in addressing the reversibility issue of metallic Zn anode towards high-performance aqueous zinc ion batteries. In view of the flourish electrolyte additive approach, the review is organized to discuss the influence of electrolyte additive on the electrolyte-Zn chemistry for the representative zinc electrolytes. Accordingly, the effects of electrolyte additives on the fundamental physicochemical properties of electrolytes, Zn surface, and Zn deposition are discussed and summarized. Based on the revealed roles of additives in interface reaction across current literature, we further provide outlook and perspective on current issues of the additive approach and potential directions.

电解质调节在解决金属锌阳极对高性能水性锌离子电池的可逆性问题中起着关键作用。鉴于蓬勃发展的电解液添加剂方法，组织综述讨论了电解液添加剂对代表性锌电解液的电解液-锌化学的影响。因此，讨论和总结了电解质添加剂对电解质、锌表面和锌沉积的基本物理化学性质的影响。基于当前文献中添加剂在界面反应中所揭示的作用，我们进一步提供了关于添加剂方法和潜在方向的当前问题的展望和观点。