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Covalently Linked Hexakis(m-Phenylene Ethynylene) Macrocycles as Molecular Nanotubes
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2023-05-04 , DOI: 10.1002/anie.202303242
Cheng-Yan Wu 1 , Shilong Su 1 , Xi Zhang 1 , Rui Liu 1 , Bing Gong 2 , Zhong-Lin Lu 1
Affiliation  

A strategy for constructing organic nanotubes with defined lengths was developed by designing and synthesizing macrocycles with a β-alanine linker. Oligomeric hexakis(m-phenylene ethynylene) macrocycles with four macrocyclic units as molecular nanotubes can form potassium and proton channels across lipid bilayers, with the channels being open continuously for over 60 s.

中文翻译:

共价连接的六(间亚苯基乙炔)大环化合物作为分子纳米管

通过设计和合成具有β-丙氨酸连接体的大环化合物,开发了构建具有限定长度的有机纳米管的策略。具有四个大环单元的低聚六(间亚苯基乙炔基)大环作为分子纳米管可以在脂质双层上形成钾和质子通道,通道连续开放超过60 s。
更新日期:2023-05-04
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